Magnetic sorbents from galvanic sludge for oily wastewater treatment

Summary

The results of studying the properties of sorbents prepared from galvanic sludge in relation to oil products are presented. For the synthesis, the method of solution combustion synthesis was chosen. Glycine was used as a reducing agent in a stoichiometric ratio with the oxidizing agent. X-ray phase analysis of the obtained samples showed that they contained iron mainly in the form of a magnetite phase. The total static exchange capacity and specific surface area of the synthesized sorbent samples (up to 130 m²/g) were determined from the sorption of the methylene blue dye. The oil capacity of the obtained materials (up to 3 g/g) is not inferior to the natural sorbents of oil products. Preparing magnetic oil sorbents is possible by the combined use of waste iron and nickel-containing galvanic sludges resulting in the reduction of the negative anthropogenic impact on the environment and elimination of the expensive technologies.

Key words

oil products , wastewater treatment , sorbent , exothermic combustion in solutions , galvanic sludges

Modified anthracites as effective catalytic materials for deironing of undergroundwater

Summary

The results of the study of modified anthracite as one of the most promising filtering materials that can be used in water treatment for undergroundwater deironing are presented. Anthracite granules were coated with iron oxides by exothermic combustion in solutions in a muffle furnace. Iron-containing sludge from water treatment plants was used as a precursor of iron. The effect of four different reducing agents on the surface-phase composition and properties of modified materials was studied. Using the method of exothermic combustion in solutions anthracite granules were modified with the formation of finely dispersed and crystalline structures of iron oxides on their surface. This had a positive effect on the catalytic ability of the material to underground water deironing. The catalytic properties of the obtained samples and the efficiency of deironing of underground water were investigated.

Key words

deferrization , water treatment , anthracite , filter bed , exothermic combustion in solutions , deironing plant sludge

Sorbent for oily wastewater treatment based on the wastes of de-ironing plants

Summary

The results of studying the properties of a sorbent obtained by the synthesis of nanosized iron oxides from the sludge generated during purification of wash water of de-ironing filters are presented. The method of exothermic combustion in solutions was chosen for the synthesis. Citric acid and hexamethylenetetramine were used as reducing agents in a stoichiometric ratio according to the reaction equation. X-ray phase analysis of the obtained samples showed the predominant presence of a magnetite phase and, at temperatures above 600°C, an additional hematite phase. The total static exchange capacity and specific surface area of the synthesized sorbent samples (up to 186.6 m²/g) were determined from the sorption of methylene blue dye. The sorbent capacity of the materials obtained (up to 3.1 g/g) is not inferior to the existing sorbents of oil products. Obtaining magnetic oil sorbents is possible eliminating the use of expensive technologies but with the simultaneous use of waste from de-ironing plants which will provide for reducing the negative anthropogenic impact on the environment and obtaining an economic effect at least by reducing the cost of production.

Key words

oil products , wastewater treatment , filter bed , sorbent , exothermic combustion in solutions , deironing plant sludge