№10|2011

DRINKING WATER SUPPLY

bbk 000000

UDC 543.33

Kashkarova G. P., Rybentsova I. A., Margolin S. L., Vorobyova E. V.

The experience of measuring aluminium ion in water

Summary

Practical use of the measuring techniques (specified in ПНД Ф 14.1:2:4.166-2000 and State Standard ГОСТ 18165-89) revealed a number of defaults in the process of determining low concentrations of aluminium in water. The technique of measurement is using the effect of aluminium-aluminon complex coloration with different chemical dosing methods. The experimental investigations showed that replacing successive addition of low concentrations of chemicals with reaction mixture improves the reproducibility of the results. However, the estimate accuracy of measurements (below 0.1 mg/l concentration) carried out with the certified aluminium determination techniques were not reached. Thus, the metrological performance of ПНД Ф 14.1:2:4.166-2000 and State Standard ГОСТ 18165-89 technique have to be revised the more especially that they have been widely used.

Key words

, , , , ,

 

Download (PDF)

 

SPISOK LITERATURY

  1. PND F 14.1:2:4.166-2000. Kolichestvennyi khimicheskii analiz vod. Metodika vypolneniia izmerenii massovoi kontsentratsii aliuminiia v probakh prirodnykh, ochishchennykh stochnykh i pit'evykh vod fotometricheskim metodom s aliuminonom.
  2. GOST 18165-89. Voda pit'evaia. Metod opredeleniia massovoi kontsentratsii aliuminiia.
  3. Kashkarova G. P., Rybentsova I. A., Margolin S. L. Otsenka dostovernosti metrologicheskikh pokazatelei PND F 14.1:2:4.166-2000 // Voda pit'evaia. 2010. № 4 (58).
  4. Tikhonov V. N. Analiticheskaia khimiia aliuminiia. – M.: Nauka, 1971.
  5. Dvorkin V. I. Metrologiia i obespechenie kachestva kolichestvennogo khimicheskogo analiza. – M.: Khimiia, 2001.
  6. Derffel' K. Statistika v analiticheskoi khimii: Per. s angl. – M.: Mir, 1994.
  7. GOST R ISO 5725-2-2002. Tochnost' (pravil'nost' i pretsizionnost') metodov i rezul'tatov izmerenii. Chast' 2. Osnovnoi metod opredeleniia povtoriaemosti i vosproizvodimosti standartnogo metoda izmerenii.
  8. RMG 76-2004. Vnutrennii kontrol' kachestva rezul'tatov kolichestvennogo khimicheskogo analiza.

Banner Oct 2024

myproject msk ru

Баннер конференции г. Пятигорск

souz ingenerov 02

Aquatherm 200x200 gif ru foreign

 

Авторизация

Внимание! Рекомендуется просматривать сайт максимально свежими версиями браузеров. Устаревшие версии не смогут корректно скачать материалы номеров журнала.