№4|2026

WASTEWATER TREATMENT

UDC 628.339:66.066.3
DOI 10.35776/VST.2026.04.03

Alekseyev E. V., Bukina Ol’ga

Coalescence in wastewater treatment technology: specifics and methods

Summary

Characteristics of water-immiscible organic liquids in wastewater from the perspective of the treatment process using coalescence are considered. With the presented material attempts are made to summarize and systematize the information on the natural phenomenon of coalescence that is determined by the physicochemical properties of water-immiscible liquids; to structure the information on the processes occurring during coalescence and the factors influencing them. The main types of emulsified organic liquids in water, including macroemulsions, microemulsions, and nanoemulsions, and their properties are discussed. The key stages of interaction between organic liquid droplets and water resulting in natural demulsification are identified, including droplet transport, droplet collisions, film drainage, film rupture, and droplet coalescence. A classification of coalescence intensification methods and materials used is proposed based on the additional energy required. Demulsification methods are presented for the main types of emulsions in wastewater.

Key words

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For citation: Alekseev E. V., Bukina O. V. Coalescence in wastewater treatment technology: specifics and methods. Vodosnabzhenie i Sanitarnaia Tekhnika, 2026, no. 4, pp. 22–29. DOI: 10.35776/VST.2026.04.03. (In Russian).

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REFERENCES

  1. Lan D., Liang B., Bao C. et al. Marine oil spill risk mapping for accidental pollution and its application in a coastal city. Marine Pollution Bulletin, 2015, v. 96, is. 1–2, рр. 220–225. DOI: 10.1016/j.marpolbul.2015.05.023.
  2. Акимова А. С., Филиппова Л. С. Проблема загрязнения поверхностных и сточных вод нефтью и нефтепродуктами и пути ее решения // Международный научно-исследовательский журнал. 2023. № 3. Вып. 129. DOI: 3-129-2023-march /10.23670/IRJ.2023.129.63.
    Akimova A. S., Filippova L. S. [The problem of surface and waste water pollution with oil and oil products and ways of solution]. Mezhdunarodnyi Nauchno-Issledovatel’skii Zhurnal, 2023, no. 3, is. 129. DOI: 3-129-2023-march/10.23670/IRJ.2023.129.63. (In Russian).
  3. Воробьева Е. В. Исследование коллоидных свойств нефтезагрязненных сточных вод и разработка способов их очистки // Вестник Томского государственного архитектурно-строительного университета. 2022. № 24 (4). С. 165–176. DOI: 10.31675/1607-1859-2022-24-4-165-176.
    Vorob’eva E. V. [Studying colloidal properties of oil-contaminated wastewater and developing treatment methods]. Vestnik Tomskogo Gosudarstvennogo Arkhitekturno-Stroitel’nogo Universiteta, 2022, no. 24 (4), pp. 165–176. DOI: 10.31675/1607-1859-2022-24-4-165-176. (In Russian).
  4. Алексеев Е. В. Физико-химические процессы очистки сточных вод: монография. – М.: Издательство АСВ, 2022. 302 с.
    Alekseev E. V. Fiziko-khimicheskie protsessy ochistki stochnykh vod [Physico-chemical processes of wastewater treatment]. Monograph. Moscow, ASV Publ., 2022, 302 p.].
  5. Partha Kundu, Akanksha Agrawal, Haaris Mateen, Indra M. Mishra. Stability of oil-in-water macro-emulsion with anionic surfactant: Effect of electrolytes and temperature. Chemical Engineering Science, 2013, v. 102, рр. 176–185.
  6. Mullins O. C. Review of the molecular structure and aggregation of asphaltenes and petroleomics. SPE Journal, 2008, v. 13, pp. 48–57.
  7. Daiane de O. D., Colombo M., Kelmann R. G. et al. Optimization of Copaiba oil-based nanoemulsions obtained by different preparation methods. Industrial Crops and Products, 2014, v. 59, pp. 154–162.
  8. Akbas E., Soyler B., Oztop M. H. Formation of capsaicin loaded nanoemulsions with high pressure homogenization and ultrasonication. LWT – Food Science and Technology, 2018, v. 96, pp. 266–273. DOI: 10.1016/j.lwt.2018.05.043.
  9. Adeyemi I., Meribout M., Khezzar L. Recent developments, challenges, and prospects of ultrasound-assisted oil technologies. Ultrasonics Sonochemistry, 2021, v. 82, article id. 105902. DOI: 10.1016/j.ultsonch.2021.105902.
  10. Avantika Kaushik, Dinesh Joshi, Rohit Kumar Saw, et al. Formation and characterization of nanoparticle assisted surfactant stabilized oil-in-water nanoemulsions for application in enhanced oil recovery. Journal Fuel, 2024, v. 359, article id. 130500. DOI: 10.1016/j.fuel.2023.130500.
  11. Koroleva M. Yu., Yurtov E. V. Ostwald ripening in macro- and nanoemulsions. Russian Chemical Reviews, 2021, no. 90 (3), pp. 293–323. DOI: 10.1070/RCR4962.
  12. Jain Mariyate, Achinta Bera. A critical review on selection of microemulsions or nanoemulsions for enhanced oil recovery. Journal of Molecular Liquids, 2022, v. 353, article id. 118791. DOI: 10.1016/j.molliq.2022.118791.
  13. I. D. G. Mayun Permana, Lutfi Suhendra, Bambang Admadi Harsojuwono, Ida Bagus Wayan Gunam. Microemulsion characteristics of oil-in-water with surfactants as α-tocopherol carriers. Journal of Analytical & Environmental Chemistry, 2024, no. 25 (1), pp. 126–134.
  14. Singh C. J., Mukhopadhyay S., Rengasamy R. S. Fibrous coalescence filtration in treating oily wastewater: A review. Journal of Industrial Textiles, 2022, v. 51 (3), pp. 3648–3682. DOI: 10.1177/15280837211040863.
  15. Dragan D. Govedarica, Radmila M. Šećerov Sokolović, Arpad I. Kiralj, Olga M. Govedarica et al. Separation of mineral oil droplets using polypropylene fibre bed coalescence. Hemijska Industrija, 2015, no. 69 (4), pp. 339–345. DOI: 10.2298/hemind140322047g.
  16. Abdulredha M. M., Jones J. T., Neustadter E. L., Whittingham K. P. Water-oil emulsion stability and demulsification via surface-active compounds: A review. Journal of Petroleum Science and Engineering, 2022, v. 209, article id. 109848. DOI: 10.1016/ j.petrol.2021.109848.
  17. Jamaly S., Giwa A., Hasan S. W. Recent improvements in oily wastewater treatment: Progress, challenges, and future opportunities. Journal of Environmental Sciences, 2015, v. 37, pp. 15–30. DOI: 10.1016/j.jes.2015.04.011.

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