Purification of water with high permanent hardness and salinity

Summary

Chemical softening methods have been widely used in the practice of water treatment, primarily in the energetics and industry for softening, decarbonization and decoloration of water. In combination with reverse osmosis, they provide for preparing water of the required qualitative composition. In drinking water supply softening methods are used quite rarely due to a number of circumstances, such as the need to use various chemicals that are not typical for public water supply; generation of a large volume of sludge subject to subsequent processing, and, what is most important, resulting in highly alkaline water with pH of more than 10 unacceptable for drinking water. However, in case only but water sources with such a complex composition are available, then chemical methods have to be used. In Mediana-Filter Research and Production Company, JSC studies were carried out to obtain high-quality water from an underground source of uncharacteristic salt composition, with a high content of sulfates and low alkalinity, provided that the purification technology should generate minimum liquid waste. After testing several technology options in pilot plants, a scheme was proposed that met the requirements of the customer. It should be noted that underground water of the southern regions of the country has a partially similar salt composition, so the results of pilot tests can also be applied to obtain drinking water from similar sources.

Key words

reagent treatment , flow chart of treatment , reverse osmosis , desalination , hardness , pilot plant , sulphates , water , dynamic softening system , liming , sodium liming , soda softening , sludge blanket , dynamic softening system water conditioning

UDC 628.33:627.834
DOI 10.35776/VST.2023.12.07

Martynenko Grigorii, Naimanov A. Ia., Naimanova Asiiat

Purification of mine water of a non-ferrous metal mine in a pilot plant

Summary

The results of pilot studies of liming, coagulation, sorption and ion exchange are presented to determine the efficiency of removing contaminants from the mine water of a non-ferrous metal mine to meet the MPC values for fishery reservoirs. Mine water is polluted with suspended substances, ions of copper, manganese, iron, zinc and nickel, petroleum products and nitrates, as well as with a small amount of feces. The pilot plant provides for two stage treatment: first, chemical-free sedimentation, addition of chlorine, lime, coagulant and flocculant, and clarification in a vertical settling tank-clarifier with polymer «brushes» in the top media. At the second stage, primary water is filtrated through parallelly installed a sodium cation exchanger filter and a sorption filter. The plant capacity was 1 m3/h. Studies were carried out on water purification in different seasons of the year with significant fluctuations in the quality indicators. It was established that the proposed process flow scheme provided for removing the main pollutants to meet the requirements for the effluent discharge into a fishery reservoir.

Key words

suspended substances , coagulation , sorption , ion exchange , liming , purification of mine water , copper and manganese ions

UDC 628.16.066.1:628.164-92
DOI 10.35776/VST.2023.08.01

Bobinkin V. V., Vukolov Oleg, Gizzatullin Artur, Kasatochkin A. S., Kostylev Evgenii, Larionov S. Iu., Oliunin Sergei, Panteleev Aleksei, Riabchikov Boris, Савочкин А. Ю., Shilov Mikhail

Industrial horizontal intensified clarifier for water
softening/decarbonization by liming

Summary

Chemical softening methods have been widely used in the water treatment practice. As shown in the previous review, the chemistry of the process has remained unchanged over the past 100 years; however, the instrumentation of the process has changed. This equates to significantly increase the capacity and efficiency of the devices. Research work has been carried out on designing domestic intensified apparatus for softening/decarbonization of water by liming; and their introduction into industrial practice has started. Studies of the developed version of the multi-chamber horizontal clarifier with liming of Aquafloc type were carried out. The boundary parameters of the process of water liming with coagulation with iron salts were determined. It was established that the improved mixing, acceleration of chemical reactions and recirculation of carbonate sludge (seed) provide for the optimization of the sedimentation process to reduce the coagulant consumption and significantly improve the sludge characteristics. Essential advantages of the clarifier are as follows: smaller dimensions and metal consumption compared to classical clarifiers, as well as a short time to reach the operating mode. Thereby, an Aquafloc clarifier can be delivered to the site ready assembled, ready-to-use and with anti-corrosion protection that significantly reduces the time and cost of assembling at the facility. The concentration of dry matter in sludge reaches 8%. In comparison with the existing VTI-630 clarifiers, Aquafloc clarifier showed similar results in terms of chemical parameters and the best in terms of the concentration of suspended solids. In terms of water consumption for own needs, the clarifier turned out to be at the level of VTI apparatus that have a total blowdown volume of 2–4%.

Key words

coagulation , suspended layer , hardness , enhanced treatment , water , mixing , chemical water softening , liming , horizontal clarifier

UDC 628.16.066.1:628.164-92
DOI 10.35776/VST.2023.03.03

Савочкин А. Ю., Kasatochkin A. S., Panteleev Aleksei, Riabchikov Boris, Larionov S. Iu., Gizzatullin Artur

Designing horizontal clarifiers and studying the efficiency of the water liming process

Summary

Chemical softening methods have been widely used in water treatment. As shown in the previous review, the chemistry of the process has remained unchanged for the past 100 years; however, the instrumentation has changed. This provides for increasing significantly the capacity of the devices and their efficiency. Mediana-Filter R&P JSC carried out research on the development of domestic intensified devices. The studies were carried out in a small-scale laboratory three-chambered horizontal clarifier with a lamellar settling tank and in a pilot clarifier with a variable chamber volume. The optimal procedure of introducing chemicals, the minimum and optimal residence time of water in the clarifier chambers have been determined. The achieved rate of the upward flow in the zone of clarification in the boundary conditions was 25 m/h. The data obtained was taken as a basis ground for designing industrial apparatuses.

Key words

suspended layer , hardness , water , mixing , chemical water softening , liming , horizontal clarifier

UDC 628.16.066.1:628.164-92
DOI 10.35776/VST.2023.01.04

Riabchikov Boris, Panteleev Aleksei, Larionov S. Iu., Савочкин А. Ю., Shilov Mikhail, Kasatochkin A. S.

Current state of the development of installations for water softening/decarbonization by liming (a review)

Summary

Chemical softening methods have been widely used in water treatment to reduce hardness and decarbonize water. The chemistry of the process has remained unchanged for the last 100 years, however, the instrumentation and some nuances of the technology are changing, i. e., the use of devices (lamellar blocks) for stabilizing flow and improving sludge settling, the use of flocculants and introduction of sludge formation centers (recirculation of activated sludge, microsand), etc. A separate method is the adoption of horizontal multi-chamber apparatus with mechanical mixing. This method provides for increasing significantly the capacity and efficiency of the apparatus. Modern ways of development of such apparatus and technologies in the Russian Federation and overseas are considered.

Key words

suspended layer , hardness , water , mixing , chemical water softening , liming , installations

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